The production of hydrogen peroxide (H2O2) is a key parameter for the performance of pulsed discharges submerged in water utilized as advanced oxidation process. So far, any related assessment of the underlying mechanism was conducted for the application of several hundred discharges, which did not allow for a correlation with physical processes. Moreover, the production was rarely investigated depending on water conductivity as one of the most important parameters for the development of submerged discharges. Accordingly, hydrogen peroxide generation was investigated here for individual single discharge events instigated with 100 ns high-voltage pulses in water with three different conductivities and was associated with the discharge development, i. e. spatial expansion and dissipated electrical energy. The approach necessitated the improvement of an electrochemical flow injection analysis based on the reaction of Prussian blue with H2O2. Hydrogen peroxide concentrations were quadratically increasing with propagation time and stable for different water conductivities. H2O2 production per unit volume of a discharge was constant over time with an estimated rate constant of 3.2 mol ⋅ m−1 s−1, averaged over the crosssectional area of all discharge filaments. However, the individually dissipated energy increased with conductivity, hence, the production efficiency decreased from 6.1 g ⋅ kWh−1 to 1.4 g ⋅ kWh−1, which was explained by increased resistive losses within the bulk liquid. 相似文献
This paper describes a new phenomenon of acoustic streaming which takes place when a Helmholtz resonator is excited by an
inside sound source with resonant frequency, and takes the form of a strong turbulent jet. The flow visualizations, hot wire
and LDV measurements are combined to investigate the process of acoustic streaming. It is found that this kind of acoustic
streaming results from the contribution of Reynolds stress. 相似文献
A theory of atmospheric icing due to freezing rain on an overhead line conductor (OHLC) is developed. The rain falls vertically on a horizontal OHLC that is thermally insulated. It is assumed that the collection efficiency of the accretion surface is unity and that this surface is in thermodynamic equilibrium with the environment.
For air temperature TA 0°C and raindrop temperature TD 0°C, the freezing rain accretes as rime ice, provided that the temperature of the ice surface Tl < 0°C. The evolution equation governing the mass transfer at the accretion surface is solved analytically, yielding the shape of the rime-ice surface. Equations governing the thermal state of the rime-ice deposit are also given. These determine the onset of wet growth or glaze accretion at the upper stagnation line during suitable environmental conditions.
For environmental conditions producing an ice surface at temperature Tl = 0°gC, the freezing accretes as glaze. Equations governing the heat and mass transfer at the surface determine the shape of the glaze surface and the downward viscous motion of the unfrozen water. For TD < 0°C, glaze evolution equations are developed for TA 0°C and TA 0°C. Analytical solutions of these equations are obtained. In particular, when TD < −TA < 0°C, the evolution equation predicts a novel limiting growth that is triangular in shape. Further study of the mass and heat transfer conditions, in the neighborhood of this final stage of glaze accretion, shows that it is maintained in thermodynamic equilibrium with its warm air environment. 相似文献
The evolution of disturbances in a hypersonic viscous shock layer on a flat plate excited by slow-mode acoustic waves is considered
numerically and experimentally. The parameters measured in the experiments performed with a free-stream Mach number M∞ = 21 and Reynolds number ReL = 1.44 · 105 are the transverse profiles of the mean density and Mach number, the spectra of density fluctuations, and growth rates of
natural disturbances. Direct numerical simulation of propagation of disturbances is performed by solving the Navier-Stokes
equations with a high-order shock-capturing scheme. The numerical and experimental data characterizing the mean flow field,
intensity of density fluctuations, and their growth rates are found to be in good agreement. Possible mechanisms of disturbance
generation and evolution in the shock layer at hypersonic velocities are discussed.
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Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 47, No. 5, pp. 3–15, September–October, 2006. 相似文献
We analyze the dynamical coupling between energy sources and structural response that must not be ignored in real engineering problems, since real motors have limited output power. 相似文献